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International Baccalaureate IB Chemistry
4.2.1 Bond‑breaking and bond‑forming energies
Bond‑breaking absorbs and bond‑forming releases energy. Calculate the enthalpy change of a reaction from given average bond enthalpy data.
4.2.2 Hess’s law
Hess’s law states that the enthalpy change for a reaction is independent of the pathway between the initial and final states. Apply Hess’s law to calculate enthalpy changes in multistep reactions.
4.2.3 Combustion & Formation ΔH
Standard enthalpy changes of combustion ($\Delta H_c^\circ$) and formation ($\Delta H_f^\circ$) data are used in thermodynamic calculations. Deduce equations and solve problems involving these terms.
4.2.4 Calculate Reaction Enthalpy
Calculate enthalpy changes of a reaction using $\Delta H_f^\circ$ data or $\Delta H_c^\circ$ data: $\Delta H^\circ = \sum \Delta H_f^\circ(\text{products}) - \sum \Delta H_f^\circ(\text{reactants})$ or $\Delta H^\circ = \sum \Delta H_c^\circ(\text{reactants}) - \sum \Delta H_c^\circ(\text{products})$.